Probability Generating Function defines Probability Distribution

Theorem
Let $X$ and $Y$ be discrete random variables whose codomain, $\Omega_X$, is a subset of the natural numbers $\N$.

Let the probability generating functions of $X$ and $Y$ be $\Pi_X \left({s}\right)$ and $\Pi_Y \left({s}\right)$ respectively.

Then:
 * $\forall s \in \left[{-1 \,.\,.\,. 1}\right]: \Pi_X \left({s}\right) = \Pi_Y \left({s}\right)$

iff:
 * $\forall k \in \N: \Pr \left({X = k}\right) = \Pr \left({Y = k}\right)$

That is, discrete random variables which are integer-valued have the same PGFs iff they have the same PMF.

Proof
By the definition of PGF, it follows that if:
 * $\forall k \in \N: \Pr \left({X = k}\right) = \Pr \left({Y = k}\right)$

then:
 * $\forall s \in \left[{-1 \,.\,.\,. 1}\right]: \Pi_X \left({s}\right) = \Pi_Y \left({s}\right)$

Suppose that $\Pi_X \left({s}\right) = \Pi_Y \left({s}\right)$ for all $s \in \left[{-1 \,.\,.\,. 1}\right]$.

From Probability Generating Function as Expectation the radius of convergence of both $\Pi_X \left({s}\right)$ and $\Pi_Y \left({s}\right)$ is at least $1$.

Therefore they have unique power series expansions about $s = 0$:
 * $\displaystyle \Pi_X \left({s}\right) = \sum_{n \mathop = 0}^\infty s^n \Pr \left({X = k}\right)$
 * $\displaystyle \Pi_Y \left({s}\right) = \sum_{n \mathop = 0}^\infty s^n \Pr \left({Y = k}\right)$

As $\Pi_X \left({s}\right) = \Pi_Y \left({s}\right)$, these two power series have identical coefficients.

Hence the result.