Class is Proper iff Bijection from Class to Proper Class
Theorem
Let $A$ be a class.
Let $\mathrm P$ be a proper class.
Then $A$ is proper if and only if there exists a bijection from $A$ to $\mathrm P$.
Corollary
$A$ is proper if and only if there exists a bijection from $P$ to $A$.
Proof
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Necessary Condition
Suppose that $A$ is a proper class.
Then by the Axiom of Limitation of Size there exists a bijection $f: A \to \mathrm U$, where $\mathrm U$ is the universal class.
There also exists a bijection $g: \mathrm P \to \mathrm U$.
By Inverse of Bijection is Bijection, there exists a bijection $g^{-1}: \mathrm U \to \mathrm P$
From Composite of Bijections is Bijection, it follows that $f \circ g^{-1}: A \to \mathrm P$ is a bijection.
$\Box$
Sufficient Condition
Suppose that there exists a bijection $f: A \to \mathrm P$.
Because $\mathrm P$ is a proper class, it follows from the Axiom of Limitation of Size that there exists a bijection $g: \mathrm P \to \mathrm U$.
Then by Composite of Bijections is Bijection, $f \circ g: A \to \mathrm U$ is a bijection from $A$ to the universe.
And so by the Axiom of Limitation of Size, $A$ is proper.
Hence the result.
$\blacksquare$